SafetyDataSheet
ShellSpiraxG80W-90
1.IDENTIFICATIONOFTHESUBSTANCE/PREPARATIONANDCOMPANY/UNDERTAKINGProductCodeInfosafeNo.IssuedDate
ProductType/UseOtherNames
001A0595
ACJ18GB/eng/C28/08/2003
Transmissionoil.Name
ShellSpiraxG80W-90
TelephoneNumbersEmergencyTel.0151-350-4595
Telephone/FaxNumberTel:0151-350-4000
Code
140001012369
Supplier
ShellUKProductsLtd
StanlowManufacturingComplexPOBox3
EllesmerePortCH654HB
TechnicalContact:ProductHSEDepartmentUNITEDKINGDOM
2.COMPOSITION/INFORMATIONONINGREDIENTSPreparationDescription
Highlyrefinedmineraloilsandadditives.Thehighlyrefinedmineraloilcontains<3%(w/w)DMSO-extract,accordingtoIP346.
DangerousComponents/Constituents
Exposurelimitsapplytothefollowingcomponents:Highlyrefinedmineraloil.
NameOlefinsulphideAlkenylamineCAS-112-90-3EINECS-204-015-5Proportion1-3%0.1-0.9%HazardC,Xn,NRPhraseR53R34,R43,R22,R50OtherInformation
SeeSection16'OtherInformation'forfulltextofeachrelevantRiskPhrase.3.HAZARDSIDENTIFICATIONECClassificationNotclassifiedasDangerousunderECcriteria.HumanHealthHazards
Nospecifichazardsundernormaluseconditions.Prolongedorrepeatedexposuremaygiverisetodermatit-is.Usedoilmaycontainharmfulimpurities.SafetyHazards
Notclassifiedasflammable,butwillburn.
VersionNo.1.128/08/2003Page1of8
ShellSpiraxG80W-90
EnvironmentalHazards
Notclassifiedasdangeroustotheenvironment.4.FIRSTAIDMEASURESSymptomsandEffects
Notexpectedtogiverisetoanacutehazardundernormalconditionsofuse.Maycauseanallergicskinreac-tioninsensitiveindividuals.
Inhalation
Intheunlikelyeventofdizzinessornausea,removecasualtytofreshair.Ifsymptomspersist,obtainmedicalattention.
Skin
Removecontaminatedclothingandwashaffectedskinwithsoapandwater.Ifpersistentirritationoccurs,ob-tainmedicalattention.Whenusinghighpressureequipment,injectionofproductundertheskincanoccur.Ifhighpressureinjuriesoccur,thecasualtyshouldbesentimmediatelytoahospital.Donotwaitforsymptomstodevelop.
Eye
Flusheyewithcopiousquantitiesofwater.Ifpersistentirritationoccurs,obtainmedicalattention.Ingestion
Donotinducevomiting.Washoutmouthwithwaterandobtainmedicalattention.
AdvicetoDoctor
Treatsymptomatically.Aspirationintothelungsmayresultinchemicalpneumonitis.Dermatitismayresultfromprolongedorrepeatedexposure.Highpressureinjectioninjuriesrequirepromptsurgicalinterventionandpossiblysteroidtherapy,tominimisetissuedamageandlossoffunction.
Becauseentrywoundsaresmallanddonotreflecttheseriousnessoftheunderlyingdamage,surgicalex-plorationtodeterminetheextentofinvolvementmaybenecessary.Localanaestheticsorhotsoaksshouldbeavoidedbecausetheycancontributetoswelling,vasospasmandischaemia.Promptsurgicaldecompres-sion,debridementandevacuationofforeignmaterialshouldbeperformedundergeneralanaesthetics,andwideexplorationisessential.
Theremaybearisktohealthwherelowviscosityproductsareaspiratedintothelungsfollowingvomiting,al-thoughthisisuncommoninadults.Suchaspirationwouldcauseintenselocalirritationandchemicalpneu-monitis.Children,andthoseinwhomconsciousnessisimpaired,willbemoreatrisk.Emesisoflubricantsisnotusuallynecessary,unlessalargeamounthasbeeningested,orsomeothercompoundhasbeendis-solvedintheproduct.Ifthisisindicated,forexample,whenthereisrapidonsetofcentralnervoussystemde-pressionfromlargeingestedvolume-gastriclavageundercontrolledhospitalconditions,withfullprotectionoftheairwayisrequired.Supportivecaremayincludeoxygen,arterialbloodgasmonitoring,respiratorysup-port,and,ifaspirationhasoccurred,treatmentwithcorticosteriodsandantibiotics.Seizuresshouldbecon-trolledwithDiazepam,orappropriateequivalentdrug.5.FIREFIGHTINGMEASURESSpecificHazards
Combustionislikelytogiverisetoacomplexmixtureofairbornesolidandliquidparticulatesandgases,in-cludingcarbonmonoxideandunidentifiedorganicandinorganiccompounds.
ExtinguishingMedia
Foamanddrychemicalpowder.Carbondioxide,sandorearthmaybeusedforsmallfiresonly.UnsuitableExtinguishingMedia
Waterinjet.Useofhalonextinguishersshouldbeavoidedforenvironmentalreasons.
VersionNo.1.128/08/2003Page2of8
ShellSpiraxG80W-90
ProtectiveEquipment
Properprotectiveequipmentincludingbreathingapparatusmustbewornwhenapproachingafireinacon-finedspace.
6.ACCIDENTALRELEASEMEASURESPersonalPrecautions
Avoidcontactwithskinandeyes.WearPVC,Neopreneornitrilerubbergloves.WearrubberkneelengthsafetybootsandPVCJacketandTrousers.Wearsafetyglassesorfullfaceshieldifsplashesarelikelytooc-cur.
EnvironmentalPrecautions
Preventfromspreadingorenteringintodrains,ditchesorriversbyusingsand,earth,orotherappropriatebarriers.Informlocalauthoritiesifthiscannotbeprevented.
Clean-upMethods-SmallSpillages
Absorbliquidwithsandorearth.Sweepupandremovetoasuitable,clearlymarkedcontainerfordisposalinaccordancewithlocalregulations.
Clean-upMethods-LargeSpillages
Preventfromspreadingbymakingabarrierwithsand,earthorothercontainmentmaterial.Reclaimliquiddir-ectlyorinanabsorbent.Disposeofasforsmallspills.7.HANDLINGANDSTORAGEHandling
Uselocalexhaustventilationifthereisriskofinhalationofvapours,mistsoraerosols.Avoidprolongedorre-peatedcontactwithskin.Whenhandlingproductindrums,safetyfootwearshouldbewornandproperhand-lingequipmentshouldbeused.Preventspillages.Cloth,paperandothermaterialsthatareusedtoabsorbspillspresentafirehazard.Avoidtheiraccumulationbydisposingofthemsafelyandimmediately.Inadditiontoanyspecificrecommendationsgivenforcontrolsofriskstohealth,safetyandtheenvironment,anassess-mentofrisksmustbemadetohelpdeterminecontrolsappropriatetolocalcircumstances.Exposuretothisproductshouldbereducedaslowasreasonablypracticable.ReferenceshouldbemadetotheHealthandSafetyExecutive'spublication'COSHHEssentials'.
Storage
Keepinacool,dry,well-ventilatedplace.Useproperlylabelledandcloseablecontainers.Avoiddirectsun-light,heatsources,andstrongoxidizingagents.ThestorageofthisproductmaybesubjecttotheControlofPollution(OilStorage)(England)Regulations.Furtherguidancemaybeobtainedfromthelocalenvironmentalagencyoffice.
StorageTemperatures
0ºCMinimum.50ºCMaximum.
RecommendedMaterials
Forcontainersorcontainerlinings,usemildsteelorhighdensitypolyethylene.UnsuitableMaterials
Forcontainersorcontainerlinings,avoidPVC.
OtherInformation
Polyethylenecontainersshouldnotbeexposedtohightemperaturesbecauseofpossibleriskofdistortion.8.EXPOSURECONTROLS,PERSONALPROTECTIONExposureLimits
VersionNo.1.128/08/2003Page3of8
ShellSpiraxG80W-90
SubstanceOilmist,mineralRegulationsEH402005EH402005ExposureDura-tionTWASTELExposureLimit510Unitsmg/m3mg/m3NotesEH402005EH402005HealthandSafetyExecutive.EH40;WorkplaceExposureLimits
ExposureControls
TheuseofpersonalprotectiveequipmentisonlyoneaspectofanintegratedapproachtotheControlOfSub-stancesHazardoustoHealth.
ThemanagementofHealthandSafetyatWorkRegulations1992requireemployerstoidentifyandevaluatetheriskstohealthandtoimplementappropriatemeasurestoeliminateorminimisethoserisks.Thechoiceofpersonalprotectiveequipmentishighlydependentuponlocalconditions,e.g.exposuretootherchemicalsubstancesandmicro-organisms,thermalhazards(protectionfromextremesofcoldandheat),electricalhazards,mechanicalhazardsandappropriatedegreeofmanualdexterityrequiredtoundertakeanactivity.Whilstthecontentofthissectionmayinformthechoiceofpersonalprotectiveequipmentused,thelimitationsofanyinformationwhichcanbeprovidedmustbefullyunderstood,e.g.personalprotectiveequipment
chosentoprotectemployeesfromoccasionalsplashesmaybeentirelyinadequateforactivitiesinvolvingpar-tialorcompleteimmersion.Ifthelevelsofoilmistorvapourinairarelikelytoexceedtheoccupationalexpos-urestandardsthenconsiderationshouldbegiventotheuseoflocalexhaustventilationtoreducepersonalexposure.
Thechoiceofpersonalprotectiveequipmentshouldonlybeundertakeninthelightofafullriskassessmentbyasuitablyqualifiedcompetentperson(e.g.aprofessionallyqualifiedoccupationalhygienist).
Effectiveprotectionisonlyachievedbycorrectlyfittingandwellmaintainedequipmentandemployersshouldensurethatappropriatetrainingisgiven.Allpersonalprotectiveequipmentshouldberegularlyinspectedandreplacedifdefective.ReferenceshouldbemadetoHSE'spublicationMethodsfortheDeterminationofHaz-ardousSubstances(MDHS)84-Measurementofoilmistfrommineraloil-basedmetalworkingfluids.Meas-urementofanemployee'sexposuretooilvapourmaybesupplementedthroughtheuseofstaintubes.Inthefirstinstance,furtherguidancemaybeobtainedthroughHSE'spublication'COSHH-abriefguidetotheregu-lations'(INDG136(rev1)).
RespiratoryProtection
Atstandardtemperatureandpressure,theOccupationalExposureStandardforoilvapourisunlikelytobeexceeded.Careshouldbetakentokeepexposuresbelowapplicableoccupationalexposurelimits.Ifthiscannotbeachieved,useofarespiratorfittedwithanorganicvapourcartridgecombinedwithaparticulatepre-filtershouldbeconsidered.Halfmasks(EN149)orvalvedhalfmasks(EN405)incombinationwithtypeA2(EN141)andP2/3(EN143)pre-filtersmaybeconsidered.
HandProtection
Chemicalprotectiveglovesaremadefromawiderangeofmaterials,butthereisnosingleglovematerial(orcombinationofmaterials)whichgivesunlimitedresistancetoanyindividualorcombinationofsubstancesorpreparations.Theextentofthebreakthroughtimewillbeaffectedbyacombinationoffactorswhichincludepermeation,penetration,degradation,usepattern(fullimmersion,occasionalcontacts)andhowthegloveisstoredwhennotinuse.
Theoreticalmaximumlevelsofprotectionareseldomachievedinpracticeandtheactuallevelofprotectioncanbedifficulttoassess.Effectivebreakthroughtimeshouldbeusedwithcareandamarginofsafetyshouldbeapplied.HSEguidanceonprotectiveglovesrecommendsa75%safetyfactortobeappliedtoanyfiguresobtainedinalaboratorytest.Nitrileglovesmayofferrelativelylongbreakthroughtimesandslowpermeationrates.Testdata,e.gbreakthroughdataobtainedthroughteststandardEN374-3:1994areavailablefromreputableequipmentsuppliers.
Personalhygieneisakeyelementofeffectivehandcare.Glovesmustonlybewornoncleanhands.Afterusinggloves,handsshouldbewashedanddriedthoroughly.Anonperfumedmoisturisershouldbeapplied.
VersionNo.1.128/08/2003Page4of8
ShellSpiraxG80W-90
EyeProtection
GogglesconformingtoaminimumstandardofEN166345Bshouldbeconsideredifthereisapossibilityofeyecontactwiththeproductthroughsplashing.Higherratedeyeprotectionmustbeconsideredforhighlyhazardousoperationsorworkareas.Forexample,employeesinvolvedinmetalworkingoperationssuchaschipping,grindingorcuttingmayrequireadditionalprotectiontoavertinjuryfromfastmovingparticlesorbrokentools.
BodyProtection
Minimiseallformsofskincontact.Overallsandshoeswithoilresistantsolesshouldbeworn.Launderover-allsandundergarmentsregularly.
EnvironmentalExposureControls
Minimisereleasetotheenvironment.Anenvironmentalassessmentmustbemadetoensurecompliancewithlocalenvironmentallegislation.
9.PHYSICALANDCHEMICALPROPERTIESColour
PhysicalStateOdourpHValue
VapourPressureInitialBoilingPointSolubilityinWaterDensityFlashPoint
FlammableLimits-UpperFlammableLimits-LowerAuto-IgnitionTemperatureKinematicViscosityEvaporationRate
VapourDensity(Air=1)
Partitionco-efficient,n-octanol/waterPourPoint
Amber.
Liquidatambienttemperature.Characteristicmineraloil.Datanotavailable.
Expectedtobelessthan0.5Paat20°C.Expectedtobeabove280°C.Negligible.
900kg/m3at15ºC.180ºC(COC).10%(V/V).1%(V/V).
Expectedtobeabove320ºC.160mm2/sat40ºC.Datanotavailable.Greaterthan1.
LogPowexpectedtobegreaterthan6.-27ºC.
10.STABILITYANDREACTIVITYStabilityStable.
ConditionstoAvoid
Extremesoftemperatureanddirectsunlight.MaterialstoAvoid
Strongoxidizingagents.
HazardousDecompositionProducts
Hazardousdecompositionproductsarenotexpectedtoformduringnormalstorage.11.TOXICOLOGICALINFORMATIONBasisforAssessment
Toxicologicaldatahavenotbeendeterminedspecificallyforthisproduct.Informationgivenisbasedonaknowledgeofthecomponentsandthetoxicologyofsimilarproducts.
VersionNo.1.128/08/2003Page5of8
ShellSpiraxG80W-90
AcuteToxicity-Oral
LD50expectedtobe>2000mg/kg.AcuteToxicity-Dermal
LD50expectedtobe>2000mg/kg.
AcuteToxicity-Inhalation
Notconsideredtobeaninhalationhazardundernormalconditionsofuse.EyeIrritation
Expectedtobeslightlyirritating.SkinIrritation
Expectedtobeslightlyirritating.
RespiratoryIrritation
Ifmistsareinhaled,slightirritationoftherespiratorytractmayoccur.SkinSensitisation
Notexpectedtobeaskinsensitizer.
Carcinogenicity
Productisbasedonmineraloilsoftypesshowntobenon-carcinogenicinanimalskin-paintingstudies.Othercomponentsarenotknowntobeassociatedwithcarcinogeniceffects.Mutagenicity
Notconsideredtobeamutagenichazard.ReproductiveToxicity
Notconsideredtobetoxictoreproduction.
OtherInformation
Prolongedand/orrepeatedcontactwiththisproductcanresultindefattingoftheskin,particularlyatelevatedtemperatures.Thiscanleadtoirritationandpossiblydermatitis,especiallyunderconditionsofpoorpersonalhygiene.Skincontactshouldbeminimised.Highpressureinjectionofproductintotheskinmayleadtolocalnecrosisiftheproductisnotsurgicallyremoved.Usedoilsmaycontainharmfulimpuritiesthathaveaccumu-latedduringuse.Theconcentrationofsuchimpuritieswilldependonuseandtheymaypresentriskstohealthandtheenvironmentondisposal.ALLusedoilshouldbehandledwithcautionandskincontactavoidedasfaraspossible.
12.ECOLOGICALINFORMATIONBasisforAssessment
Ecotoxicologicaldatahavenotbeendeterminedspecificallyforthisproduct.Informationgivenisbasedonaknowledgeofthecomponentsandtheecotoxicologyofsimilarproducts.
Mobility
Liquidundermostenvironmentalconditions.Floatsonwater.Ifitenterssoil,itwilladsorbtosoilparticlesandwillnotbemobile.
Persistence/Degradability
Notexpectedtobereadilybiodegradable.Majorconstituentsareexpectedtobeinherentlybiodegradable,buttheproductcontainscomponentsthatmaypersistintheenvironment.Bioaccumulation
Containscomponentswiththepotentialtobioaccumulate.
Ecotoxicity
Poorlysolublemixture.Maycausephysicalfoulingofaquaticorganisms.Productisexpectedtobepracticallynon-toxictoaquaticorganisms,LL/EL50>100mg/l.(LL/EL50expressedasthenominalamountofproductrequiredtoprepareaqueoustestextract).Mineraloilisnotexpectedtocauseanychroniceffectstoaquaticorganismsatconcentrationslessthan1mg/l.
VersionNo.1.128/08/2003Page6of8
ShellSpiraxG80W-90
OtherAdverseEffects
Notexpectedtohaveozonedepletionpotential,photochemicalozonecreationpotentialorglobalwarmingpotential.
Productisamixtureofnon-volatilecomponents,whicharenotexpectedtobereleasedtoairinanysignific-antquantities.
13.DISPOSALCONSIDERATIONSWasteDisposal
Recycleordisposeofinaccordancewithprevailingregulations,byarecognisedcollectororcontractor.Thecompetenceofthecontractortodealsatisfactorilywiththistypeofproductshouldbeestablishedbeforehand.Donotpollutethesoil,waterorenvironmentwiththewasteproduct.ProductDisposalAsforwastedisposal.
ContainerDisposal
Recycleordisposeofinaccordancewiththelegislationinforcewitharecognisedcollectororcontractor.14.TRANSPORTINFORMATIONTransportInformation
NotdangerousfortransportunderADR/RID,IMOandIATA/ICAOregulations.15.REGULATORYINFORMATIONECSymbolsECRiskPhraseECSafetyPhraseEINECSTSCA(USA)None.Notclassified.Notclassified.Allcomponentslistedorpolymerexempt.Allcomponentslisted.NationalLegislation
EnvironmentalProtectionAct1990(asamended).HealthandSafetyatWorkAct1974ConsumersProtectionAct1987ControlofPollutionAct1974EnvironmentalAct1995FactoriesAct1961
CarriageofDangerousGoodsbyRoadandRail(Classification,PackagingandLabelling)RegulationsChemicals(HazardInformationandPackagingforSupply)Regulations2002.ControlofSubstancesHazardoustoHealthRegulations1994(asamended).RoadTraffic(CarriageofDangerousSubstancesinPackages)RegulationsMerchantShipping(DangerousGoodsandMarinePollutants)Regulations
RoadTraffic(CarriageofDangerousSubstancesinRoadTankersinTankContainers)RegulationsRoadTraffic(TrainingofDriversofVehiclesCarryingDangerousGoods)RegulationsReportingofInjuries,DiseasesandDangerousOccurencesRegulationsHealthandSafety(FirstAid)Regulations1981
PersonalProtectiveEquipment(ECDirective)Regulations1992PersonalProtectiveEquipmentatWorkRegulations1992
Packaging&Labelling
Containsalkenylamine.Mayproduceanallergicreaction.Safetydatasheetavailableforprofessionaluseronrequest.
VersionNo.1.128/08/2003Page7of8
ShellSpiraxG80W-90
16.OTHERINFORMATIONRevisionsHighlighted
Toassistharmonisationofsdsauthoringpractices,aversionnumberhasbeenintroduced.
References
GUIDANCENOTES
UKChemicalsRegulatoryAtlas,AnOverviewofhowtoguideyourchemicalthroughtoregulatorycompli-ance(DTI).
HSG71Thestorageofpackageddangeroussubstances.EH/40OccupationalExposureLimits.
EH/58TheCarcinogenicityofMineralOils.
MS24Healthsurveillanceofoccupationalskindisease.
HSG53Theselection,useandmaintenanceofrespiratoryprotectiveequipment:Apracticalguide.
HSG206Costandeffectivenessofchemicalprotectiveglovesfortheworkplace:Guidanceforemployersandhealthandsafetyspecialists.
L74FirstAidatwork:ApprovedCodeofPracticeandGuidance.HSG136Workplacetransportsafety:guidanceforemployers.
INDG234(rev)AreyouInvolvedintheCarriageofDangerousGoodsbyRoadorRailOTHERLITERATURE
ConcaweReport3/82PrecautionaryAdviceontheHandlingofUsedEngineOilsConcaweReport86/69HealthAspectsofWorkerExposuretoOilMists
ConcaweReport01/97PetroleumProducts-FirstAidEmergencyandMedicalAdvice
ConcaweReport01/53ClassificationandlabellingofpetroleumsubstancesaccordingtotheEUdangeroussubstancesdirective(ConcawerecommendationsAugust2001)
ConcaweReport01/54environmentalclassificationofpetroleumsubstancessummarydataandrationaleConcaweReport5/02amendedsafetydatasheetdirective(2001/58/EC)
DepartmentoftheEnvironment-WasteManagement-TheDutyofCare-ACodeofPracticeConcawe,Boulevarddusouverain165B-1160Brussels,Belgiumwww.concawe.be
Restrictions
ThisproductmustnotbeusedinapplicationsotherthanrecommendedwithoutfirstseekingtheadviceoftheSHELLtechnicaldepartment.
ListofRPhrasesinSection2R22Harmfulifswallowed.R34Causesburns.
R43Maycausesensitizationbyskincontact.R50Verytoxictoaquaticorganisms.
R53Maycauselongtermadverseeffectsintheaquaticenvironment.TechnicalContactNumbers0151-350-4000.
FurtherInformation
Thisinformationisbasedonourcurrentknowledgeandisintendedtodescribetheproductforthepurposesofhealth,safetyandenvironmentalrequirementsonly.Itdoesnotconstituteaguaranteeforanyspecificpropertyoftheproduct....EndOfSDS...
VersionNo.1.128/08/2003Page8of8
因篇幅问题不能全部显示，请点此查看更多更全内容